熔点 | 160°C |
敏感性 | 对热、空气和湿度敏感 |
存贮条件 | 储存温度-20°C,充氩保存 |
应用 |
Tetrakis(acetonitrile)copper(I) hexafluorophosphate can be employed as a catalyst for the synthesis of triazolo[1,2-a]indazole-1,3,8-trione and 2H-indazolo[2,1-b]phthalazine-trione derivatives by the reaction of aryl aldehydes, dimedone and urazole or phthalhydrazide, respectively. It can also be used as a copper precursor: · For the formation of Cu2S/CdS nanorod junctions by cationic exchange process. · To synthesize monometallic copper macrocyclic biquinazoline ligand [Cu(Mabiq)]. · To prepare the cuprous complex [Cu(2-iQBO)(POP)]PF6]; where 2-iQBO=2-(1′-isoquinolyl)benzoxazole and POP=bis[2-(diphenylphosphino)phenyl]ether, which can form luminescent pseudo-polymorphs. · For the synthesis of [Cu(NHC)2]PF6 complexes [(NHC = N-heterocyclic carbene] which can be further used in the hydrosilylation of carbonyl compounds. |
别名 | 四乙腈铜(I)六氟磷酸盐;;Copper(I)tetrakis(acetonitrile)hexafluorophosphate; Cuprous tetrakis(acetonitrile) hexafluorophosphate |