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目标: • Develop a reverse phase HPLC method to detect triazine herbicides (propazine, atrazine, ter-butylazine, simazine and irgarol) using a single quadrupole MS detector with field free APCI source • Determine the detection limits for 5 triazine herbicides • Study the effect of a nitrogen supply hydrocarbon trap on sensitivity determination of 5 triazine herbicides • Study the fragmentation pattern of triazine herbicides compounds using APCI and capillary exit collision induced decomposition (CID) in positive ionization mode 方法 HPLC: PerkinElmer Flexar™FX-10 MS: PerkinElmer Flexar™SQ 300 MS with PerkinElmer field free APCI source Column: PerkinElmer Brownlee Supra C18, 3 µm, 2.1 x 100 mm Gradient: 60 % MeOH to 85 % MeOH in water, 5 mM ammonium formate in 7 min at 0.5 mL/min APCI source temperature: 300℃ Corona Current: 5 µA