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Aminothiols Sensing Based on Fluorosurfactant-Mediated Triangular Gold Nanoparticle-Catalyzed Luminol Chemiluminescence Qianqian Li,Fang Liu,Chao Lu,Jin-Ming Lin J. Phys. Chem. C 2011, 115, 10964 – 10970 State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, China Department of Chemistry, Tsinghua University, Beijing 100084, China ABSTRACT: A novel method was used to synthesize triangular gold nanoparticles (AuNPs) (i.e., trisodium citrate reduction of HAuCl4 in the presence of nonionic fl uorosurfactant). The as-prepared triangular AuNPs owned higher surface-to-volume ratio and more active surface sites compared to spherical AuNPs, which facilitated the active oxygen intermediates generation and electron-transfer processes on the surface of trian-gular AuNPs. Therefore, it was first found that triangular AuNPs displayed greater catalytic activity (ca. 125-fold) toward luminol chemiluminescence (CL) than spherical AuNPs. More inter-estingly, ultratrace aminothiols (ca. 0.1 nM) can interrupt the formation of the active oxygen intermediates by forming Au-S covalent bonds on the surface of triangular AuNPs, resulting in a great decrease in CL intensity, while the other biomolecules including 19 standard amino acids, alcohols, organic acids, and saccharides have no effect on triangular AuNPs-catalyzed luminol CL signals. These significant features of triangular AuNPs-catalyzed luminol CL were the ability to detect aminothiols in the presence of other essential amino acids and biomolecules.