1,2-双(二苯基膦)苯
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1,2-双(二苯基膦)苯

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上海阿拉丁生化科技股份有限公司
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产品特点
规格信息
货号 CAS号
B301761-1g 13991-08-7
B301761-25g 13991-08-7
B301761-5g 13991-08-7
B129163-1g 13991-08-7
B129163-250mg 13991-08-7
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产品描述
  • 分子式 C6H4[P(C6H5)2]2
  • 分子量446.46
  • Beilstein号
  • EC号
  • MDL号 MFCD00014081
  • PubChem编号

属性

熔点 183-188°C
敏感性 对空气敏感
溶解性 Insoluble in water.
存贮条件 充氩储存

描述

应用 1,2-Bis(diphenylphosphino)benzene (DPPB) can be used:
· As a chelating ligand in the synthesis of luminescent copper(I) halide complexes.
· In the synthesis of copper-1,2-bis(diphenylphosphino)benzene catalyst which is used for the β-boration of α, β-unsaturated amide.
· As an alternative to TMEDA for the selective cleavage of sp3 C-X bond in fluoroaromatic coupling reactions catalyzed by iron.
· As a ligand in the synthesis of alkenylboronates from acetylenic esters.
· To synthesize copper-diphosphine complexes which are used as homogeneous catalysts for N-formylation of a wide range of amines
别名 1,2-双(二苯基磷基)苯;1,2-双(联苯代磷基)-苯;dppbz;o-双(二苯基膦)苯, 邻苯基双 [二苯基膦];1,2-双(二苯基磷基)苯;dppbz; 1,2-Bis(diphenylphosphanyl)benzene; dppbe; dppben; dppbenz; dppbz; o-Phenylenebis[diphenylphosphine]; o-bis(diphenylphosphino)benzene
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