货号 | CAS号 |
---|---|
C102805-100g | 16523-54-9 |
C102805-1g | 16523-54-9 |
C102805-25g | 16523-54-9 |
C102805-5g | 16523-54-9 |
沸点 | 165 °C/12 mmHg |
折光率 | 1.533 |
敏感性 | 对空气和湿度敏感 |
溶解性 | Reacts violently with water |
存贮条件 | 充氩保存 |
密度 | 1****** |
应用 |
Chlorodicyclohexylphosphine can be used as a reactant in the synthesis of: · 1,2-Bis(dicyclohexylphosphinoxy)ethane ligand by reacting with ethylene glycol in the presence of triethylamine via Michaelis?Arbuzov type rearrangements. · 1,1,2,2-tetracyclohexyldiphosphine monosulfide ligand by treating with LiS. It can be also used as a starting material for the preparation of some other ligands such as dicyclohexylphosphine oxide , phosphino substituted N-aryl pyrroles , di-tert-butyl((dicyclohexylphosphino)methyl)phosphine , dicyclohexylcyclopentylphosphine. These ligands are used in Pd-catalyzed cross-coupling reactions. |
别名 | 二-环己基氯化膦;二环己氯化膦;二环己氯膦;氯代二环己基膦;二环己基次膦酰氯;二环己基氯膦;Dicyclohexylchlorophosphine; Dicyclohexylphosphine chloride; Dicyclohexylphosphinous chloride |