货号 | CAS号 |
---|---|
X111327-100g | 161265-03-8 |
X111327-1g | 161265-03-8 |
X111327-25g | 161265-03-8 |
X111327-5g | 161265-03-8 |
熔点 | 226-230°C |
溶解性 | Soluble in organic solvents |
应用 | 有机试剂,医药中间体。用于催化反应的金属螯合配体。用作通过 3-溴噻吩和 2-氨基吡啶的钯催化 C-N 交叉偶联反应合成杂环的配体。也可用于活泼亚甲基化合物和醇参与的钌催化烷基化反应。 |
产品介绍 | 4,5-Bis(diphenylphosphino)-9,9-dimethylxanthene is a metal chelating ligand for catalysis. 4,5-Bis(diphenylphosphino)-9,9-dimethylxanthene is also a ligand used in the synthesis of heterocycles by palladium-catalyzed C-N cross coupling of 3-bromothiophenes with 2-aminopyridines. The compound has been used in a ruthenium-catalyzed alkylation of active methylene compounds with alcohols. |
别名 | 4,5-双(苯甲酰硫基)-9,9-二甲基呫吨;9,9-二甲基-4,5-双(二苯基磷)占吨;4,5-双(二苯基膦)-二苯并吡喃衍生物;4,5-双(二苯基膦基)-9,9-二甲基氧杂蒽;4,5-双(二苯基膦)-9,9-二甲基氧杂蒽; ;9,9-Dimethyl-4,5-bis(diphenylphosphino)xanthene; Dimethylbisdiphenylphosphinoxanthene; 4,5-Bis(diphenylphosphino)-9,9-dimethylxanthene Xantphos |