应用 |
1-Phenyl-1-trimethylsiloxyethylene has been used in the synthesis of:
. β-amino ketones in water via Mannich-type reaction
. cis-2,6-disubstituted dihydropyrans via three-component, one-pot cascade reaction |
产品介绍 |
1-Phenyl-1-trimethylsiloxyethylene is a styrene type silyl enol ether, reacts with formaldehyde and 2,4-pentanedione to yield the corresponding dihydropyran. It also undergoes Mukaiyama aldol reaction with aldehydes in water in the presence of amphiphilic calix[6]arene derivatives as surfactants. |
别名 |
α-(三甲基硅氧基)苯乙烯;1-苯基-1-三甲基甲硅氧基乙烯;α-(Trimethylsilyloxy)styrene |