1，1-硫代羰基二咪唑

属性

熔点	97-105°C
敏感性	对湿度敏感
溶解性	Soluble in terahydrofuran, toluene and dichloromethane.
存贮条件	储存温度 2-8°C，充氩保存
密度	1.3900

描述

应用	合成硫代酰胺的试剂；从醇中制备硫代甲酸酯，期间要和Bu3SnH-AIBN3剧烈反应。 · 1,1′-Thiocarbonyldiimidazole (TCDI) is generally used as a reagent to carry out the deoxygenation of vicinal diols by forming cyclic thionocarbonate in Corey-Winter alkene synthesis. · It is used as a reagent in the enantioselective total synthesis of (+)-hapalindole Q, 12-epi-fischerindole U and welwitindolinone A. · It is also used in the preparation of trithiocarbonates, xanthates, and dithiocarbamates as chain transfer agents for the reversible addition fragmentation chain transfer and macromolecular design (RAFT/ MADIX) polymerization.
产品介绍	溶于水并分解。
别名	1,1'-硫羰基二咪唑;1-1'-巯基羧基二咪唑;N,N'-硫代羰基二咪唑;1,1-硫代羰基二咪唑;N,N'-硫羰基二咪唑;1,1'-Carbonothioylbis-1H-imidazole; 1,1'-Thiocarbonyldiimidazole; TCDI; 1,1'-Thiocarbonylbis(imidazole)

Reaxys-RN	609349
标识符号	GHS07
信号词	Warning
危害声明	H315,H319
警示性声明	P264,P280,P302+P350,P305+P351+P338,P332+P313,P337+P313,P362
个人防护设备	Eyeshields,Gloves,type N95 (US),type P1 (EN143) respirator filter
WGK德国	3
风险声明 (欧洲)	R22;R34;
安全声明（欧洲）	S26;S36/37/39/;S45;