| 应用 |
(tert-Butyldimethylsilyl)acetylene may be used in the synthesis of β-alkynylketone[1] and β-alkynyl aldehydes. |
| 产品介绍 |
(tert-Butyldimethylsilyl)acetylene is a bulky trialkylsilyl-protected alkyne. It participates in Cadiot-Chodkiewicz cross-coupling reaction with various bromoalkynes to afford synthetically useful unsymmetrical diynes.
(tert-Butyldimethylsilyl)acetylene readily undergoes cross-dimerization reaction with various internal phenyl acetylenes in the presence of rhodium dimers and bidentate phosphine ligands to afford enynes. |
| 别名 |
叔丁基乙炔基二甲基硅烷;叔丁基二甲基硅烷乙炔;(tert-Butyl)ethynyldimethylsilane;tert-Butyldimethylsilylacetylene |
