[(三叔丁基膦)-2-(2-氨基联苯基)]氯化钯(II)

属性

熔点	167-170 °C
敏感性	空气及湿度敏感
存贮条件	充氩保存

描述

应用	P(t-Bu)3 Pd G2 (Chloro[(tri-tert-butylphosphine)-2-(2-aminobiphenyl)] palladium(II), Pd/P(t-Bu)3) may be used as catalyst in the following studies: . Synthesis of sterically hindered biaryls (tetra-ortho-substituted), via cross-coupling reactions of aryl chlorides. . Stille cross-couplings reactions of aryl chloride. . Synthesis of chloropeptin I, via Stille cross-coupling reaction. . Heck reaction. . Negishi cross-coupling reactions.
产品介绍	P(t-Bu)3 Pd G2 (Chloro[(tri-tert-butylphosphine)-2-(2-aminobiphenyl)] palladium(II)) is a second generation (G2) precatalyst containing a biphenyl-based ligand. Product participates in various palladium catalyzed cross-coupling reactions, C-C, C-N and C-O bond formation reactions, and Suzuki-Miyaura coupling reactions. It generates active Pd catalyst at room temperature in the presence of weak phosphate or carbonate bases. It has been proposed as an active catalyst for use in Stille reactions of aryl halides (bromides and chlorides).
别名	;P(t-Bu)3 Pd G2

Reaxys-RN	22750896
WGK德国	3