13.060.50 (Examination of water for chemical subst 标准查询与下载

ASTM D1688-02 水中铜含量的标准试验方法

1.1 These test methods cover the determination of copper in water by atomic absorption spectrophotometry. Three test methods are included as follows: Concentration Range SectionsTest Method A-Atomic Absorption, Direct0.05 to 5 mg/L7-15Test Method B-Atomic Absorption, Chelation-Extraction50 to 500 956;g/L16-24Test Method C-Atomic Absorption, Graphite Furnace5 to 100 956;g/L25-331.2 Either dissolved or total recoverable copper may be determined. Determination of dissolved copper requires filtration through a 0.45-m (No. 325) membrane filter at the time of collection. In-line membrane filtration is preferable.1.3 The values stated in SI units are to be regarded as the standard. The values given in parentheses are provided for information only.1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. For specific hazard statements, see Note 3, Note 5, Note 8, and Note 13.1.4 Three former photometric test methods were discontinued. Refer to for historical information.

Standard Test Methods for Copper in Water

ASTM D1126-02(2007)e1 水硬度的标准试验方法

Hardness salts in water, notably calcium and magnesium, are the primary cause of tube and pipe scaling, which frequently causes failures and loss of process efficiency due to clogging or loss of heat transfer, or both. Hardness is caused by any polyvalent cations, but those other than Ca and Mg are seldom present in more than trace amounts. The term hardness was originally applied to water in which it was hard to wash; it referred to the soap-wasting properties of water. With most normal alkaline water, these soap-wasting properties are directly related to the calcium and magnesium content.1.1 This test method covers the determination of hardness in water by titration. This test method is applicable to waters that are clear in appearance and free of chemicals that will complex calcium or magnesium. The lower detection limit of this test method is approximately 2 to 5 mg/L as CaCO3; the upper limit can be extended to all concentrations by sample dilution. It is possible to differentiate between hardness due to calcium ions and that due to magnesium ions by this test method.1.2 This test method was tested on reagent water only. It is the user's responsibility to ensure the validity of the test method for waters of untested matrices.This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

Standard Test Method for Hardness in Water

ASTM D1067-02 水的酸度或强碱性的标准测试方法

1.1 These test methods cover the determination of acidity or alkalinity of all types of water. Three test methods are given as follows: SectionsTest Method A (Electrometric Titration) 7 to 15Test Method B (Electrometric or Color-Change Titration) 16 to 24Test Method C (Color-Change Titration After Hydrogen Peroxide Oxidation and Boiling) 25 to 331.2 In all of these test methods the hydrogen or hydroxyl ions present in water by virtue of the dissociation or hydrolysis of its solutes, or both, are neutralized by titration with standard alkali (acidity) or acid (alkalinity). Of the three procedures, Test Method A is the most precise and accurate. It is used to develop an electrometric titration curve (sometimes referred to as a pH curve), which defines the acidity or alkalinity of the sample and indicates inflection points and buffering capacity, if any. In addition, the acidity or alkalinity can be determined with respect to any pH of particular interest. The other two methods are used to determine acidity or alkalinity relative to a predesignated end point based on the change in color of an internal indicator or the equivalent end point measured by a pH meter. They are suitable for routine control purposes.1.3 When titrating to a specific end point, the choice of end point will require a careful analysis of the titration curve, the effects of any anticipated changes in composition on the titration curve, knowledge of the intended uses or disposition of the water, and a knowledge of the characteristics of the process controls involved. While inflection points (rapid changes in pH) are usually preferred for accurate analysis of sample composition and obtaining the best precision, the use of an inflection point for process control may result in significant errors in chemical treatment or process control in some applications. When titrating to a selected end point dictated by practical considerations, (1) only a part of the actual neutralizing capacity of the water may be measured, or (2) this capacity may actually be exceeded in arriving at optimum acidity or alkalinity conditions.1.4 A scope section is provided in each test method as a guide. It is the responsibility of the analyst to determine the acceptability of these test methods for each matrix.1.5 Former Test Methods C (Color-Comparison Titration) and D (Color-Change Titration After Boiling) were discontinued. Refer to for historical information.1.6 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

Standard Test Methods for Acidity or Alkalinity of Water

ASTM D4691-02(2007) 火焰原子吸收分光光度法测定水中元素的标准实施规范

Elemental constituents in water and wastewater need to be identified to support effective water quality monitoring and control programs. Currently, one of the most widely used and practical means for measuring concentrations of elements is by atomic absorption spectrophotometry. The major advantage of atomic absorption over atomic emission is the almost total lack of spectral interferences. In atomic emission, the specificity of the technique is almost totally dependent on monochromator resolution. In atomic absorption, however, the detector sees only the narrow emission lines generated by the element of interest.1.1 This practice covers general considerations for the quantitative determination of elements in water and waste water by flame atomic absorption spectrophotometry. Flame atomic absorption spectrophotometry is simple, rapid, and applicable to a large number of elements in drinking water, surface waters, and domestic and industrial wastes. While some waters may be analyzed directly, others will require pretreatment.1.2 Detection limits, sensitivity, and optimum ranges of the elements will vary with the various makes and models of satisfactory atomic absorption spectrometers. The actual concentration ranges measurable by direct aspiration are given in the specific test method for each element of interest. In the majority of instances the concentration range may be extended lower by use of electrothermal atomization and conversely extended upwards by using a less sensitive wavelength or rotating the burner head. Detection limits by direct aspiration may also be extended through sample concentration, solvent extraction techniques, or both. Where direct aspiration atomic absorption techniques do not provide adequate sensitivity, the analyst is referred to Practice D 3919 or specialized procedures such as the gaseous hydride method for arsenic (Test Methods D 2972) and selenium (Test Methods D 3859), and the cold vapor technique for mercury (Test Method D 3223).1.3 Because of the differences among various makes and models of satisfactory instruments, no detailed operating instructions can be provided. Instead the analyst should follow the instructions provided by the manufacturer of a particular instrument.This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. For specific hazard statements see Section 9.

Standard Practice for Measuring Elements in Water by Flame Atomic Absorption Spectrophotometry

ASTM D516-02 水中硫酸根离子的标准测试方法

1.1 This turbidimetric test method covers the determination of sulfate in water in the range from 1 to 40 mg/L of sulfate ion (SO 4).1.2 This test method was used successfully with drinking, ground, and surface waters. It is the user's responsibility to ensure the validity of this test method for waters of untested matrices.1.3 Former gravimetric and volumetric test methods have been discontinued. Refer to Appendix X1 for historical information.1.4 This standard does not purport to address the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

Standard Test Method for Sulfate Ion in Water

ASTM D5462-02 水中低水平溶解氧在线测量的标准试验方法

DO may be either a corrosive or passivating agent in boiler/steam cycles and is therefore controlled to specific concentrations that are low relative to environmental and wastewater treatment samples. Out-of-specification DO concentrations may cause corrosion in boiler systems, which leads to corrosion fatigue and corrosion products—all detrimental to the life and efficient operation of a power unit. The efficiency of DO removal from boiler feedwater by mechanical or chemical means, or both, may be monitored by continuously measuring the DO concentration before and after the removal process with on-line instrumentation. DO measurement is also a check for air leakage into the boiler water cycle. Guidelines for feedwater to high-pressure boilers with all volatile treatment generally require a feedwater DO concentration below 5 μg/L (3). Boiler feedwater with oxygenated treatment is maintained in a range of 50 to 300 μg/L DO (4). In microelectronics production, DO can be detrimental in some manufacturing processes, for example, causing undesirable oxidation on silicon wafers.1.1 This test method covers the on-line determination of dissolved oxygen (DO) in water samples primarily in ranges from 0 to 500 181g/L (ppb), although higher ranges may be used for calibration. On-line instrumentation is used for continuous measurements of DO in samples that are brought through sample lines and conditioned from high-temperature and high-pressure sources when necessary. 1.2 This standard does not purport to address all of the safety problems, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. For specific hazards statements, see 6.5.

Standard Test Method for On-Line Measurement of Low-Level Dissolved Oxygen in Water

ASTM D4691-02 火焰原子吸收分光光度法测定水中元素的标准实施规范

1.1 This practice covers general considerations for the quantitative determination of elements in water and waste water by flame atomic absorption spectrophotometry. Flame atomic absorption spectrophotometry is simple, rapid, and applicable to a large number of elements in drinking water, surface waters, and domestic and industrial wastes. While some waters may be analyzed directly, others will require pretreatment.1.2 Detection limits, sensitivity, and optimum ranges of the elements will vary with the various makes and models of satisfactory atomic absorption spectrometers. The actual concentration ranges measurable by direct aspiration are given in the specific test method for each element of interest. In the majority of instances the concentration range may be extended lower by use of electrothermal atomization and conversely extended upwards by using a less sensitive wavelength or rotating the burner head. Detection limits by direct aspiration may also be extended through sample concentration, solvent extraction techniques, or both. Where direct aspiration atomic absorption techniques do not provide adequate sensitivity, the analyst is referred to Practice D 3919 or specialized procedures such as the gaseous hydride method for arsenic (Test Methods D 2972) and selenium (Test Methods D 3859), and the cold vapor technique for mercury (Test Method D 3223).1.3 Because of the differences among various makes and models of satisfactory instruments, no detailed operating instructions can be provided. Instead the analyst should follow the instructions provided by the manufacturer of a particular instrument.1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. For specific hazard statements see Section 9.

Standard Practice for Measuring Elements in Water by Flame Atomic Absorption Spectrophotometry

ASTM D3372-02 水中钼含量的标准测试方法

1.1 This test method covers the determination of dissolved and total recoverable molybdenum in most waters, wastewaters, and brines by atomic absorption spectroscopy.1.2 This test method is applicable in the range from 1 to 25 956;g/L of molybdenum. The range may be extended by dilution of the sample.1.3 This test method has been used successfully with natural and reagent waters. It is the user's responsibility to ensure the validity of this test method for waters of untested matrices.1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. For specific precautionary statements, see Note 3 and Note 9.

Standard Test Method for Molybdenum in Water

ASTM D5673-02 用感应耦合等离子体质谱仪测定水中元素的标准试验方法

1.1 This test method covers the determination of dissolved elements in ground water, surface water, and drinking water. It may also be used for the determination of total-recoverable elements in these waters as well as wastewater.1.2 This test method should be used by analysts experienced in the use of inductively coupled plasma8212;mass spectrometry (ICP-MS), the interpretation of spectral and matrix interferences and procedures for their correction.1.3 It is the user's responsibility to ensure the validity of the test method for waters of untested matrices.1.4 Talbe 1 lists elements for which the test method applies, with recommended masses and typical estimated instrumental detection limits using conventional pneumatic nebulization. Actual working detection limits are sample dependent and, as the sample matrix varies, these detection limits may also vary. In time, other elements may be added as more information becomes available and as required.1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

Standard Test Method for Elements in Water by Inductively Coupled Plasma8212;Mass Spectrometry

ASTM D513-02 水中二氧化碳总溶解量的标准试验方法

1.1 These test methods provide for the measurement of total or dissolved carbon dioxide present as carbon dioxide (CO2), carbonic acid, bicarbonate ion, and carbonate ion in water:RangeSectionsTest Method A (Gas Sensing Electrode)2 to 800 mg/L8 to 15Test Method B (CO2 Evolution, Coulometric Titration)5 to 800 mg/L16 to 241.2 Carbon dioxide may also be detected from carbonates present in particulates in samples.1.3 Test Method A is applicable to various natural waters and brines.1.4 Test Method B is applicable to natural waters, brines, and various industrial waters as delineated in .1.5 It is the user's responsibility to ensure the validity of these test methods on waters of untested matrices.1.6 Several test methods were discontinued from this standard in 1988. Refer to for historical information.1.7 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

Standard Test Methods for Total and Dissolved Carbon Dioxide in Water

ASTM D6764-02(2007) 从明渠中采集水温、溶解氧浓度、具体电导性和PH值的标准指南

1.1 This guide describes procedures to collect cross-sectional means of temperature, dissolved oxygen, specific electrical conductance, and pH of water flowing in open channels.1.2 This guide provides guidelines for preparation and calibration of the equipment to collect cross-sectional means of temperature, dissolved oxygen, specific electrical conductance, and pH of water flowing in open channels.1.3 This guide describes what equipment should be used to collect cross-sectional means of temperature, dissolved oxygen, specific electrical conductance, and pH of water flowing in open channels.1.4 This guide covers the cross-sectional means of temperature, dissolved oxygen, specific electrical conductance, and pH of fresh water flowing in open channels.This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory requirements prior to use.

Standard Guide for Collection of Water Temperature, Dissolved-Oxygen Concentrations, Specific Electrical Conductance, and pH Data from Open Channels

ASTM D3865-02 水中钚的标准试验方法

This test method was developed to measure plutonium in environmental waters or waters released to the environment, and to determine whether or not the plutonium concentration exceeds the maximum amount allowable by regulatory statutes.1.1 This test method covers the determination of alpha-particle-emitting isotopes of plutonium concentrations over 0.01 Bq/L (0.3 pCi/L) in water by means of chemical separations and alpha pulse-height analysis (alpha-particle spectrometry). The isotopes, 239Pu, 240Pu, and 238Pu, are chemically separated from a 1-L water sample by coprecipitation with ferric hydroxide, anion exchange and electrodeposition. The test method applies to soluble plutonium and to suspended particulate matter containing plutonium. In the latter situation, an acid dissolution step is required to assure that all of the plutonium dissolves.1.2 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. Specific hazards are given in Section 9.

Standard Test Method for Plutonium in Water

ASTM D1691-02 水中锌含量的标准试验方法

1.1 These test methods cover the determination of zinc in water. Two test methods are given as follows:SectionsTest Method A-Atomic Absorption, Direct0.05 to 2 mg/L8-16Test Method B-Atomic Absorption, Chelation-Extraction20 to 200 956;g/L17-251.2 Either dissolved or total recoverable zinc may be determined.1.3 These test methods have been used successfully with reagent grade water. See the specific test method for applicability to other matrices. It is the user's responsibility to assure the validity of these test methods in other matrices.1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. For specific hazard statements, see Section 6 and Note 5, Note 8, and Note 13.1.5 Two former colorimetric test methods were discontinued. Refer to Appendix X1 for historical information.

Standard Test Methods for Zinc in Water

ASTM D858-02 水中锰含量的标准试验方法

1.1 These test methods cover the atomic absorption determination of dissolved and total recoverable manganese in water and certain wastewaters. Three test methods are given as follows: Concentration Range SectionsTest Method A-Atomic Absorption, Direct 0.1 to 5 mg/L7 to 15Test Method B-Atomic Absorption, Chelation-Extraction 10 to 500 956;g/L 16 to 24Test Method C-Atomic Absorption, Graphite Furnace 5 to 50 956;g/L25 to 331.2 Test Methods A, B, and C were used successfully on reagent grade and natural waters. Other matrices used in the study were brine (Test Method B), effluent from a wood treatment plant, and condensate from a medium Btu coal gasification process (Test Method C). It is the user's responsibility to ensure the validity of a test method for waters of untested matrices. 1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. For specific hazard statements, see 11.7.1, 20.2, 20.9 and 22.10.1.4 Former Test Method A (Colorimetric) was discontinued. For historical information, see Appendix X1.

Standard Test Methods for Manganese in Water

ASTM D4309-02 为测定水中总的金属含量用密闭容器微波加热技术煮解样品的标准规程

1.1 This practice covers the general considerations for quantitative sample digestion for total metals in water using closed vessel microwave heating technique. This practice is applicable to surface, saline, domestic, and industrial wastewater.1.2 Because of the differences among various makes and models of satisfactory instruments, no detailed operating instructions can be provided. Instead, the analyst should follow the instructions provided by the manufacturer of the particular instrument.1.3 This practice can be used with the following ASTM standards, providing the user determines precision and bias based on this digestion practice: Test Methods D 857, Test Methods D 858, Test Methods D 1068, Specification D 1192, Test Methods D 1687, Test Methods D 1688, Test Methods D 1691, Test Methods D 1886, Practices D 3370, Test Methods D 3557, Test Methods D 3559, Practice D 3919, Test Methods D 4190, Practice D 4453, and Practice D 4691.1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. For specific hazard statements, see Section 9.

Standard Practice for Sample Digestion Using Closed Vessel Microwave Heating Technique for the Determination of Total Metals in Water

ASTM D5904-02(2009) 用紫外线、过硫酸盐氧化物和薄膜导电率检测法测定水中总含碳量、有机碳和无机碳的标准试验方法

This test method is used for determination of the carbon content of water from a variety of natural, domestic, and industrial sources. In its most common form, this test method is used to measure organic carbon as a means of monitoring organic pollutants in high purity and drinking water. These measurements are also used in monitoring waste treatment processes. The relationship of TOC to other water quality parameters such as chemical oxygen demand (COD) and total oxygen demand (TOD) is described in the literature. 1.1 This test method covers the determination of total carbon (TC), inorganic carbon (IC), and total organic carbon (TOC) in water in the range from 0.5 to 30 mg/L of carbon. Higher levels may be determined by sample dilution. The test method utilizes ultraviolet-persulfate oxidation of organic carbon, coupled with a CO2 selective membrane to recover the CO2 into deionized water. The change in conductivity of the deionized water is measured and related to carbon concentration in the oxidized sample. Inorganic carbon is determined in a similar manner without the requirement for oxidation. In both cases, the sample is acidified to facilitate CO2 recovery through the membrane. The relationship between the conductivity measurement and carbon concentration is described by a set of chemometric equations for the chemical equilibrium of CO2, HCO3−, H+, and the relationship between the ionic concentrations and the conductivity. The chemometric model includes the temperature dependence of the equilibrium constants and the specific conductances. 1.2 This test method has the advantage of a very high sensitivity detector that allows very low detection levels on relatively small volumes of sample. Also, use of two measurement channels allows determination of CO2 in the sample independently of organic carbon. Isolation of the conductivity detector from the sample by the CO2 selective membrane results in a very stable calibration, with minimal interferences. 1.3 This test method was used successfully with reagent water spiked with sodium bicarbonate and various organic materials. It is the user's responsibility to ensure the validity of this test method for waters of untested matrices. 1.4 This test method is applicable only to carbonaceous matter in the sample that can be introduced into the reaction zone. The injector opening size generally limits the maximum size of particles that can be introduced. 1.5 In addition to laboratory analyses, this test method may be applied to on line monitoring. 1.6 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard. 1.7 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

Standard Test Method for Total Carbon, Inorganic Carbon, and Organic Carbon in Water by Ultraviolet, Persulfate Oxidation, and Membrane Conductivity Detection

ASTM D4282-02(2010) 用微扩散法测定水和污水中游离氰化物的标准试验方法

This test method is useful in distinguishing between the potentially available free cyanide (total cyanide) and the free cyanide actually present. This test method provides a convenient technique for making on-site free cyanide determinations.1.1 This test method covers the determination of free cyanides in waters and wastewaters. Free cyanide is here defined as the cyanide which diffuses as cyanide (HCN), at room temperature, from a solution at pH 6. 1.2 This test method does not include complexes that resist dissociation, such as hexacyanoferrates and gold cyanide, nor does it include thiocyanate and cyanohydrin. 1.3 This test method may be applied to water and wastewater samples containing free cyanide from 10 to 150 μg/L. Greater concentrations may be determined by appropriate dilution. 1.4 This test method has been fully validated by collaborative testing as specified by Practice D2777. 1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. For specific hazard statements, see 8.6, 8.9, Section 9, and 12.2.1.

Standard Test Method for Determination of Free Cyanide in Water and Wastewater by Microdiffusion

ASTM D6764-02(2013) 开放渠道水温, 溶解氧浓度, 比电导率和pH数据收集的标准指南

5.1 This guide describes stabilization criteria for recording field measurements of Temperature, DO, SC, and pH. 5.2 This guide describes the procedures used to calibrate and check meters to be used in the field to records these measurements and the procedures to be use in the field to obtain these data. 5.3 This guide describes quality assurance procedures to be followed when obtaining cross-sectional means of temperature, dissolved oxygen, specific electrical conductance, and pH of water flowing in open channels.TABLE 1 Stabilization Criteria for Recording Field Measurements (1)Note 1—[±, plus or minus value shown; °C, degrees Celsius; ≤ less than or equal to values shown; μS/cm microsiemens at 25°C, gt;, greater than value shown; unit, standard pH unit; mg/L milligram per liter]. Standard Direct Field Measurement Stabilization Criteria for Measurements (Variability Should Be Within the Value Shown) Temperature: 8199;Electronic Temperature Sensor 8199;Liquid-in-glass thermometer ±0.2°C ±0.5°C Specific Electrical Conductance: 8199;when ≤ 100 mS/cm 8199;when gt; 100 mS/cm ±58201;% ±58201;% pH: 8199;Meter displays to 0.01 ±0.1 unit Dissolved oxygen: 8199;Amperometric method ±0.3 mg/L 5.4 Field measurement must accurately represent the water flowing in the open channel being measured. Methods need to be used that will result in an accurate representation of the mean of the parameter of interest. Procedures must be used that will take into consideration the variation in the parameter across the sections and with depth. 5.5 ......

Standard Guide for Collection of Water Temperature, Dissolved-Oxygen Concentrations, Specific Electrical Conductance, and pH Data from Open Channels

ASTM D1783-01(2012) 水中苯酚类化合物的标准试验方法

Phenolic compounds are sometimes found in surface waters from natural and industrial sources. Their presence in streams and other waterways frequently will cause off flavor in fish tissue and other aquatic food. Chlorination of waters containing phenols may produce chlorophenols that are odoriferous and objectionable tasting.1.1 These test methods cover the preparation of the sample and the determination of the concentration of phenolic compounds in water. They are based on the color reaction of phenol (C6H5OH) with 4-aminoantipyrine and any color produced by the reaction of other phenolic compounds is reported as phenol. The concentration of phenol measured represents the minimum concentration of phenolic compounds present in the sample. 1.2 Phenolic compounds with a substituent in the para position may not quantitatively produce color with 4-aminoantipyrine. However, para substituents of phenol such as carboxyl, halogen, hydroxyl, methoxyl, or sulfonic acid groups do produce color with 4-aminoantipyrine. 1.3 These test methods address specific applications as follows: RangeSections Test Method AChloroform Extraction Test Method BDirect Photometric0 to 100 μg/L >0.1 mg/L (100 μg/L)11 to 17 18 to 24 1.4 It is the users' responsibility to assure the validity of the standard test method for use in their particular matrix of interest. 1.5 This standard does not purport to address all the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. For specific hazard statements see 6.3.2 and 8.6.

Standard Test Methods for Phenolic Compounds in Water

ASTM D1783-01(2007) 水中苯酚类化合物的标准试验方法

Phenolic compounds are sometimes found in surface waters from natural and industrial sources. Their presence in streams and other waterways frequently will cause off flavor in fish tissue and other aquatic food. Chlorination of waters containing phenols may produce chlorophenols that are odoriferous and objectionable tasting.1.1 These test methods cover the preparation of the sample and the determination of the concentration of phenolic compounds in water. They are based on the color reaction of phenol (C6H5OH) with 4-aminoantipyrine and any color produced by the reaction of other phenolic compounds is reported as phenol. The concentration of phenol measured represents the minimum concentration of phenolic compounds present in the sample. 1.2 Phenolic compounds with a substituent in the para position may not quantitatively produce color with 4-aminoantipyrine. However, para substituents of phenol such as carboxyl, halogen, hydroxyl, methoxyl, or sulfonic acid groups do produce color with 4-aminoantipyrine. 1.3 These test methods address specific applications as follows: RangeSections Test Method A—Chloroform Extraction Test Method B—Direct Photometric0 to 100 μg/L >0.1 mg/L (100 μg/L)11 to 17 18 to 24 1.4 It is the users' responsibility to assure the validity of the standard test method for use in their particular matrix of interest. 1.5 This standard does not purport to address all the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. For specific hazard statements see 6.3.2 and 8.6.

Standard Test Methods for Phenolic Compounds in Water